Sunday, 11 December 2016

Revision Questions and Answers for structure and bonding



1. Which ion has the most shells that contain electrons?
a. Al3+b. Be2+
c. N3-
d. S2-
2. Which substance contains covalent bonds but also conducts electricity?
a. brass
b. graphite
c. iodine
d. steel
3. Which electron arrangement is that of a metallic element?
a. 2, 1
b. 2, 4
c. 2, 5
d. 2, 7
4. Which molecules have the same number of protons?
a. O2 and N2
b. Cl2 and Br2c. CO2 and SO2
d. CH4 and NH3
5. Metals have positive ions in a 'sea of electrons'. Which metal atom provides most electrons for the sea?
a. aluminium
b. magnesium
c. sodium
d. zinc
6. Which substance does not have a macromolecular structure?
a. diamond
b. graphite
c. silicon dioxide
d. sodium chloride
7. Which atom has the same electronic configuration as the strontium ion?
a. calcium
b. krypton
c. rubidium
d. selenium
8. Element X has an electronic structure 2.8.8.1.
Element Y has an electronic structure 2.8.6.
What is made when X and Y react?
Type of compound         Formula
a.           covalent                     X2Y
b.           covalent                     XY2
c.           ionic                          X2Y
d.           ionic                          XY2
9. What is the formula of uranium(VI) oxide?
a. U6O
b. U2O3
c. UO3
d. UO6
10. Graphite is used to make
a. glass
b. cutting tools
c. electrical wiring
d. electrodes
11. Which compound has both ionic and covalent bonds?
a. ammonium chloride
b. carbon dioxide
c. ethy ethanoate
d. sodium chloride
12. Elements X and Y react to form an ionic compound of formula XY. What could be the proton (atomic) numbers of X and Y?
   Y
 a 3
 b 6 8
 c 8 16
 d 12 16

13. An atom of an element contains 17 protons, 18 neutrons and 17 electrons. What is the atomic structure of another isotope of this element?
   protons neutrons  electrons
 a  17  20  17
 b  17  18   16
 c  18  18  17
 d  20  18  17
14. Which of the following has the highest electrical conductivity?
a. aqueous sugar solution
b. solid graphite
c. solid sodium chloride
d. gaseous carbon dioxide
15. Which of the following ions has the same number of electrons as a krypton atom, atomic number 36?
a. chlorine
b. rubidium
c. sodium
d. xenon
16. Which of the following is a compound?
a. air
b. carbon
c. oxygen
d. steam

17. In which set do the three particles each have the same total number of electrons?
 a Cl- Br-  I-
 b F- Ne Na+
 c K+ Ca2+ Br-
 d Li+ Na+ K+ 
18. An ion X+ has 23 nucleons and 10 electrons. What does the nucleus of the ion X+ contain?
   protons neutrons 
 a 12  11
 b 11 12
 c 10 13
 d 9 14
19. The table shows information about particles X and Y.
   number of protons number of neutrons   electronic structure
 X  9  10  2, 8
 Y  17  20  2, 8, 8
Which statement is correct for both X and Y?
a. they are atoms of metals
b. they are atoms of noble gases
c. they are isotopes of the same element
d. they are negative ions
20. Which substance could be sodium chloride?
 substance  melting point/oC conduction of electricity when liquid  conduction of electricity when in aqueous solution
 a  -114  none  none
 b  -114  none  good
 c  180  none  insoluble
 d  808  good  good
21. Chemical bonding involves the rearrangement of 
a. molecules
b. atoms
c. electrons
d. ions
22. Solid carbon dioxide (dry ice) is used as a refrigerating agent because it readily changes directly from the solid state into the gaseous state at a low temperature. Based on the above information, what is the main intermolecular bonding in CO2 (s) likely to be?
a. covalent bonding
b. ionic bonding
c. hydrogen bonding
d. Van der Waals forces
23. Which of the following does not contain covalent bonds?
a. graphite
b. gold
c. ice
d. diamond
24. Which atom has the same electronic configuration as the strontium ion?
a. calcium
b. krypton
c. rubidium
d. selenium
25. How does a magnesium atom form a bond with an oxygen atom?
a. by giving one pair of electrons to the oxygen atom
b. by sharing one pair of electrons, provided by the magnesium atom
c. by sharing two pairs of electrons, both pairs provided by the oxygen atom
d. by sharing two pairs of electrons, each atom donating one pair of electrons
26. In which of the following pairs do the elements form a compound by sharing electrons?
a. carbon and chlorine
b. lithium and iodine
c. neon and oxygen
d. potassium and bromine
27. Which substance does not have a macromolecular structure?
a. diamond
b. graphite
c. silicon dioxide
d. sodium chloride
28. Which substance has the highest melting point?
a. diamond
b. lead(II) bromide
c. methane
d. water
29. Substance X has a melting point higher than 500ÂșC. It is insoluble both in water and in organic solvents. It conducts electricity both when solid and when molten. What could X be?
a. copper
b. magnesium oxide
c. poly(ethene)
d. silica
30. Which of the following describes the structure of diamond?
a. a giant structure of atoms bonded covalently
b. a regular arrangement of oppositely charged ions
c. layers of rings of atoms
d. positively charged ions surrounded by a sea of electrons

MCQ Answers

1. d
2. b
3. a
4. d
5. a
6. d
7. b
8. c
9. c
10. d
11. a
12. d
13. a (isotopes of the same element have same number of protons but different number of neutrons)
14. b
15. b
16. d
17. b
18. b
19. d
20. d
21. c
22. d
23. b
24. b (both strontium ion and krypton have 36 electrons)
25. a (magnesium and oxygen undergo ionic bonding)
26. a
27. d (sodium chloride has a giant ionic structure made up of a lattice of positive and negative ions held tightly together by strong electrostatic forces of attraction - ionic bonds)
28. a (a lot of energy is needed to break the extremely strong C-C covalent bonds in diamond)
29. a
30. a

Structured Question Worked Solutions

1. Uranium-235 and uranium-238 are two isotopes of uranium. The table below shows the numbers of the particles in one atom of uranium-235
 particle Number 
 electron 92 
 neutron 143 
 proton 92 

a. suggest a reason why this is known as uranium-235

b. In the table below, give the numbers of particles found in an atom of uranium-238
 particle number 
 electron  
 neutron  
 proton  

c. Uranium-235 is radioactive and is used in the manufacture of nuclear weapons. Give one other use of uranium-235

Solutions
a. mass number = 143 + 92 = 235
b. 
 particle  number
 electron  92
 neutron  146
 proton  92
c. as a nuclear fuel in the production of nuclear energy

2. Fluorine can form either covalent or ionic bonds.
a. Draw a dot-and-cross diagram to show the bonding in
i. sodium fluoride, NaF
ii. fluorine, F2
Your diagrams must show all electrons.

b. Explain why sodium fluoride has a higher melting point than fluorine
Solutions
ai. 
aii.
b. In NaF, the ionic bonds are very strong. In F2, the forces of attraction between Fmolecules are very weak. A lot of energy is required to break the strong ionic bonds. Hence, NaF has a higher melting point than F2.
3. Use the information in the table below to answer the following questions
 substance conducts electricity when solid   melting point/oC dissolves in water 
 sodium chloride  no  808  yes
 sulphur  no  113  no
 tungsten  yes  3377  no
 wax  no  35-50  no
 aluminium  yes  660  no

ai. Name two metals from the table
aii. How can you tell from the table that the substances you have chosen in (i) are metals?

b. How can you tell from the table that wax is a mixture?

ci. Name a compound from the table
cii. Explain the meaning of the word compound

d. Describe how the arrangement and movement of particles in aluminium change as the temperature rises from 659
oC to 661oC

e. Suggest how you could separate a mixture of sulphur and sodium chloride to produce a sample of each
Solution
ai. tungsten and aluminium
aii. They conduct electricity when solid
b. Wax melts over a range of temperatures
ci. sodium chloride
cii. a compound contains 2 or more elements chemically bonded together. The ratio of each element is fixed.
d. At 659oC, the particles are vibrating vigorously about their fixed positions. At 660oC, Al starts to melt and the particles break free from each other and begin to move about in aggregates.
e. Dissolve the mixture in water and filter. Sulphur remains as residue while NaCl is collected as filtrate. NaCl can then be obtained by crystallization.
4. The table shows the atomic structure of six particles, represented by the letters L to Q. The particles are atoms or ions. The letters are not the symbols of the elements.
 particle electrons  protons  neutrons 
 L  6  6  6
 M  2  2  2
 N  12  12  12
 O  10  12  12
 P  6  6
 Q  10  13  14

Use the letters L to Q to answer the following questions.

a. Which 2 particles are ions?

b. Which particle is a atom of a noble gas?

c. Which 2 particles are an atom and an ion of the same element?

d. Which 2 particles are isotopes of the same element?

e. Which particle has the highest atomic mass?
Solutions
a. O and Q (because O is an ion with a 2+ charge while Q is an ion with a 3+ charge)
b. M 
c. N and O (N and O have the same number of protons but different number of electrons
d. L and P have the same number of protons but different number of neutrons
e. Q. (13 + 14 =27)
5. Sodium is stored under oil because it rapidly oxidises to form sodium oxide, Na2O.Draw a dot-and-cross diagram to show the bonding in sodium oxide. (Only need to show outer shell electrons)
Solution

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