Acids: The word ‘Acid’ came from Latin word ‘Acidus or Acere’ which means sour.
Sour
taste is the most common characteristic of acid. Acid turns blue litmus
paper red. There are many substances which contain acid and hence taste
sour, such as curd, tamarind, lemon, etc.
Types of Acids: Acids are divided into two types on the basis of their occurrence – Natural acids and Mineral acids.
Natural Acid: Acids which are obtained from natural sources are called natural acid or organic acid.
Mineral Acids: Acids
that prepare from mineral are known as mineral acids, inorganic acids,
man-made acids or synthetic acid, such as hydrochloric acid, sulphuric
acid, nitric acid, etc.
Organic Acids & Source | |
---|---|
Acid | Source |
Acetic acid | Vinegar |
Ascorbic acid | Guava, amla |
Citric acid | Lemon, orange and other citrus fruits |
Lactic acid | Sour milk, curd |
Methanoic acid | Ant sting, nettle sting |
Oxalic acid | Tomato |
Tartaric acid | Tamarind |
Chemical Properties of Acid
Reaction of acids with metal:
Acids give hydrogen gas along with respective salt when they react with a metal.
Example: Hydrogen gas and zinc chloride are formed when hydrochloric acid reacts with zinc metal.
Hydrogen gas and sodium chloride are formed when hydrochloric acid reacts with sodium metal.
Hydrogen gas and iron chloride are formed when hydrochloric acid reacts with iron.
Hydrogen gas and zinc sulphate are formed when zinc metal reacts with sulphuric acid
Test for hydrogen gas: The
gas evolved after reaction of acid with metal can be tested by bringing
a lighted candle near it. If the gas burns with pop sound, then it
confirms the evolution of hydrogen gas. Burning with pop sound is the
characteristic test for hydrogen gas.
Reaction of acids with metal carbonate:
Acids give carbon dioxide gas and respective salts along with water when they react with metal carbonates.
Examples: Hydrochloric acid gives carbon dioxide gas, sodium chloride along with water when reacts with sodium carbonate.
Hydrochloric acid gives carbon dioxide, magnesium chloride and water when it reacts with magnesium carbonate.
Hydrochloric acid gives carbon dioxide gas, calcium chloride and water when it reacts with calcium carbonate.
Sulphuric acid gives calcium sulphate, carbon dioxide gas, calcium sulphate and water when it reacts with calcium carbonate.
Sulphuric acid gives sodium sulphate, carbon dioxide gas and water when it reacts with sodium carbonate.
Nitric acid gives sodium nitrate, water and carbon dioxide gas when it reacts with sodium carbonate.
Reaction of acid with hydrogen carbonates (bicarbonates):
Acids give carbon dioxide gas, respective salt and water when they react with metal hydrogen carbonate.
Examples: Hydrochloric acid gives carbon dioxide, sodium chloride and water when it reacts with sodium bicarbonate.
Sulphuric acid gives sodium sulphate, carbon dioxide gas and water when it reacts with sodium bicarbonate.
Sodium bicarbonate is also known as sodium hydrogen carbonate, baking soda, baking powder, bread soda and bicarbonate of soda.
Test
for evolution of carbon dioxide gas: Carbon dioxide turns lime water
milky when passed through it. This is the characteristic test for carbon
dioxide gas.
The
gas evolved because of reaction of acid with metal carbonate or metal
hydrogen carbonate turns lime water milky. This shows that the gas is
carbon dioxide gas. This happens because of formation of white
precipitate of calcium carbonate.
But
when excess of carbon dioxide is passed through lime water, it makes
milky colour of lime water disappear. This happens because of formation
of calcium hydrogen carbonate. As calcium hydrogen carbonate is soluble
in water, thus the milky colour of solution mixture disappears.
Reaction of acid with marble and egg shell: Since,
marble and egg shell are made of calcium carbonate, hence when acid is
poured over marble or egg shell, bubbles of carbon dioxide are formed.
Historical Monuments and Acid Rain:
Burning
of fossil fuels releases oxides of sulphur and nitrogen. Nitrogen oxide
and sulphur dioxide form nitric acid and sulphuric acid on reaction
with water. When rain droplets mix with these gases; present in
atmosphere because of pollution; they form acid rain.
Acid
rain causes damage to the historical monuments and other buildings. For
example Taj Mahal, which is made of marble, is getting damaged because
of reaction with acid rain. Marble is calcium carbonate which reacts
with the acid and thus gets corroded.
Acid & Base and Fire Extinguisher
Metal
carbonate or metal hydrogen carbonate and acid are used in fire
extinguisher to produce carbon dioxide gas. Acid and metal carbonate or
bicarbonate are kept in separate chambers in a fire extinguisher. On
emergency they are allowed to react with one another. The carbon dioxide
gas so produce is poured over fire. As carbon dioxide does not support
burning, it puts off the fire.
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